Weathering of High-Density Polyethylene-Wood Plastic Composites

Due to the widespread use of wood-plastic composites (WPCs), high-density polyethylene-wood flour composites (HDPE/WF) were studied in order to determine their stability in different application conditions. UV degradation and periodic absorption/desorption of moisture cause damaging changes to material during WPCs’ exterior application, so it is necessary to ensure WPCs’ durability against atmospheric influences. Samples were characterized by FTIR spectroscopy and scanning electron microscopy (SEM) in order to study the degradation after simulated weathering. The degree of water absorption was also determined. Thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC) were used for the determination of composites’ thermal properties. Results show that the stability of the HDPE/WF composites to UV treatment highly depends on stabilizer content and its dispersion in the polymer matrix. Incompatibility of HDPE and wood particles is a major problem that should be solved to achieve good durability and satisfying properties in use.     

Simultaneous oxidation of aromatic compounds using Sr-doped lanthanum manganites as catalysts

Strontium-doped lanthanum manganites, La_1-xSr_xMnO₃ (LSMO), are promising and affordable catalysts for oxidative degradation of volatile organic compounds. LSMO catalysts (x = 0, .1, .2, and .3) were prepared by the citrate-nitrate autocombustion (CNA) and coprecipitation synthesis. The phase composition was confirmed by X-ray diffraction and Rietveld refinement analysis, while the oxygen content was determined by Mohr's salt permanganate titration. Morphology and porosity of prepared catalysts was correlated to catalytic oxidation of benzene, toluene, ethylbenzene and o-xylene. It was observed that both synthesis methods yielded catalysts of similar average pore size diameter and specific surface area, but the pore size distribution differed: CNA-prepared catalysts had a multimodal pore size distribution, while the coprecipitated ones had a single maximum at 4 nm. Catalysts prepared by the CNA method have shown a higher catalytic activity in the temperature range 373–723 K, as the presence of Mn³⁺/Mn⁴⁺ mixed valences increased their reducibility.     

An interpretation of the changes in demographic behaviour at a sub-national level using spatial measures in post-socialist countries: A case study of the Czech Republic and Slovakia

The transformation of fertility and family behaviour in post-socialist countries was quick and the changes were striking. An account of the changes is the subject of dispute and the mechanisms have still not been explained in a fully satisfying manner. Relatively little attention has been paid to the changes in spatial aspects concerning the broadening of changes in family behaviour. The aim of this paper is to answer the question as to whether changes spread stochastically in post-socialist countries or if there are obvious spatial patterns. The study tries to answer the questions whether there are any cores of changes which may be understood as innovations, if there is any spatial clustering and if the extent is hierarchically arranged.     

Determination of rock type and moisture content in flysch using TLS intensity in the Elerji quarry (south-west Slovenia)

Bulletin of Engineering Geology and the Environment - Terrestrial laser scanning (TLS) was performed in tectonically undisturbed flysch in the Elerji quarry (south-west Slovenia), which represents...     

Sphinganine‐Like Biogenesis of (E)‐1‐Nitropentadec‐1‐ene in Termite Soldiers of the Genus Prorhinotermes

In 1974, (E)‐1‐nitropentadec‐1‐ene, a strong lipophilic contact poison of soldiers of the termite genus Prorhinotermes, was the first‐described insect‐produced nitro compound. However, its biosynthesis remained unknown. In the present study, we tested the hypothesis that (E)‐1‐nitropentadec‐1‐ene biosynthesis originates with condensation of amino acids with tetradecanoic acid. By using in vivo experiments with radiolabeled and deuterium‐labeled putative precursors, we show that (E)‐1‐nitropentadec‐1‐ene is synthesized by the soldiers from glycine or L ‐serine and tetradecanoic acid. We propose and discuss three possible biosynthetic pathways.     

Assessing the performance of a spectral reflectance estimation method based on a diffraction grating and a spectroradiometer

Constant improvements in digital cameras have made it possible to use these devices for colour acquisition and reproduction at an advanced level. It is known that a colour match for all observers when changing illumination can only be achieved by matching spectral data. Obtaining spectral data from digital camera RGB values could provide a new way of using the digital camera as a spectrophotometric tool or as a high‐quality colour‐capturing system that is required in more demanding applications. In the present study, two spectral reflectance estimation methods were examined – the Imai–Berns method (ImaiBerns) and the spectral‐sensitivity‐based method (SpecSens). The purpose of the research was to simplify the procedure of the SpecSens method by using a diffraction grating and a spectroradiometer instead of a monochromator, and to compare the results with those of the ImaiBerns approach. Obtained spectral reflectance estimates were evaluated using the root‐mean‐square error and ?E₀₀ metrics. Results of the research show that the ImaiBerns method was superior to SpecSens, most likely because the former method does not require knowledge of the camera spectral sensitivities, which often introduces errors into reflectance estimation calculations. Both methods were successful in predicting black, brownish, and dark patches, as indicated by a low root‐mean‐square error, as well as unsaturated pastel, pink, or skin colours, which produced low ?E₀₀ values. On the other hand, many of the patches with a low root‐mean‐square error also exhibited high ?E₀₀ values, while bright, nearly‐white patches were characterised by a high root‐mean‐square error.     

The Chemistry and Biology of 6‐Hydroxyceramide,the Youngest Member of the Human Sphingolipid Family

Sphingolipids are crucial for the life of the cell. In land‐dwelling mammals, they are equally important outside the cell—in the extracellular space of the skin barrier—because they prevent loss of water. Although a large body of research has elucidated many of the functions of sphingolipids, their extensive structural diversity remains intriguing. A new class of sphingolipids based on 6‐hydroxylated sphingosine has recently been identified in human skin. Abnormal levels of these 6‐hydroxylated ceramides have repeatedly been observed in atopic dermatitis; however, neither the biosynthesis nor the roles of these unique ceramide subclasses have been established in the human body. In this Minireview, we summarize the current knowledge of 6‐hydroxyceramides, including their discovery, structure, stereochemistry, occurrence in healthy and diseased human epidermis, and synthetic approaches to 6‐hydroxysphingosine and related ceramides.     

Real‐Time Modelling of Fibrous Muscle

Relatively recently it has become apparent that providing human kind with a better healthcare requires personalized, predictive and integrative medicine, for which the building of virtual physiological human (VPH) framework accessible via virtual patient avatar is necessary. Real‐time modelling and visual exploration of such a complex avatar is a challenging task. In this paper, we propose a real‐time method for automatic modelling of an arbitrarily large number of muscle fibres in the volume of a muscle represented by its surface mesh. The method is based on an iterative morphing of predefined fibres template into the muscle volume exploiting harmonic scalar field computed on the surface of muscle. Experiments with muscles of thighs and pelvis show that the method produces realistic shapes of fibres. Our sequential VTK‐based C++ implementation is capable of producing 64 fine fibres within a muscle of 10K triangles in less than 170 ms on commodity hardware making the method suitable for VPH purposes as well as for interactive educational medical software.     

Visualization of the Centre of Projection Geometrical Locus in a Single Image

Single view reconstruction (SVR) is an important approach for 3D shape recovery since many non‐existing buildings and scenes are captured in a single image. Historical photographs are often the most precise source for virtual reconstruction of a damaged cultural heritage. In semi‐automated techniques, that are mainly used under practical situations, the user is the one who recognizes and selects constraints to be used. Hence, the veridicality and the accuracy of the final model partially rely on man‐based decisions. We noticed that users, especially non‐expert users such as cultural heritage professionals, usually do not fully understand the SVR process, which is why they have trouble in decision making while modelling. That often fundamentally affects the quality of the final 3D models. Considering the importance of human performance in SVR approaches, in this paper we offer a solution that can be used to reduce the amount of user errors. Specifically, we address the problem of locating the centre of projection (CP). We introduce a tool set for 3D visualization of the CP's geometrical loci that provides the user with a clear idea of how the CP's location is determined. Thanks to this type of visualization, the user becomes aware of the following: (1) the constraint relevant for CP location, (2) the image suitable for SVR, (3) more constraints for CP location required, (4) which constraints should be used for the best match, (5) will additional constraints create a useful redundancy. In order to test our approach and the assumptions it relies on, we compared the amount of user made errors in the standard approaches with the one in which additional visualization is provided.